Daily 21- the really long one

Well for the inconsistent posts here, all you CAN expect is a long visual connect to make it up :)So here goes (its fairly simple).

Connect and who's the latest?(they are hopefully in chronological order)
READ THE FULL QUESTION :
1.Connect
2. Who fills the latest slot at (20) and what's the unique specialty of it?
3. And what record do (1) and (4) hold wrt this connection?

Ok vinay got the connect right.

Here's the answer:
1) Connect - James Bond opening title songs
2) The latest one is Alicia Keys and Jack White who performed 'Another Way To Die' for the movie Quantum Of Solace which is the first Bond title duet.
3) John Barry and Shirley Bassey (1 and 4) have performed the title song for more than one Bond flick

so +1 for Vinay and nice attempt by Anand as well